Spiro-OMeTAD Sublimed 99.8% (Spiro-MeOTAD)

Model: PEROVSITE
Place of Origin: Zhejiang,China (Mainland)
Brand Name: borun
CAS No.: 207739-72-8
Purity: 99.8%
Appearance: light Yellow
Purity: 99.8%
Grade: sublimed grade
Synonym: N2,N2,N2′,N2′,N7,N7,N7′,N7′-octakis(4-methoxyphenyl)-9,9′-spirobi[9H-fluorene]-2,2′,7,7′-tetramine,
Synonym NAME: Spiro-MeOTAD

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Product Description

Payment & Shipping Terms Supply Capacity
Payment Terms:D/P, T/TProduction Capacity:500G/month
Means of Transport:AirPacking:bottle
Delivery Date:in stock

Spiro-OMeTAD (Spiro-MeOTAD) Sublimed 99.8% 

 Spiro-OMeTAD (Spiro-MeOTAD) Sublimed 99.8% is used in perovskite and OLED hole interfaces in stock now for immediate dispatch to institutions worldwide.


Specification:


CAS Registry Number207739-72-8
Molecular FormulaC81H68N4O8
Molecular Weight1225.43
Purity99.5%
Gradesublimed grade
AppearanceLight Yellow


Melting point240 °C (approx.)
TGA>360°C (0.5% weight loss)


Properties

Related CategoriesHole Transport (HT) & Hole Injection Layer (HIL) Materials, Hole Transport Materials, Materials Science, OLED and PLED Materials, Organic and Printed Electronics More...
InChI Key  XDXWNHPWWKGTKO-UHFFFAOYSA-N
assay  99% (HPLC)
mp  243-248 °C
absorption  306 nm in dichloromethane

385 nm in dichloromethane
fluorescence  λem 429 nm in dichloromethane

Properties

Related CategoriesHole Transport (HT) & Hole Injection Layer (HIL) Materials, Hole Transport Materials, Materials Science, OLED and PLED Materials, Organic and Printed Electronics More...
InChI Key  XDXWNHPWWKGTKO-UHFFFAOYSA-N
assay  99% (HPLC)
mp  243-248 °C
absorption  306 nm in dichloromethane

385 nm in dichloromethane
fluorescence  λem 429 nm in dichloromethane

Description

Packaging

1, 5,10 g in glass bottle

Application

High-mobility material used for white OLEDs to increase hole injection and transport. It is the best solid-state hole transporting material, to date, used to replace the liquid electrolyte for DSSC solar cells, due to an excellent pore-filling property in nanoporous TiO2 film with pore size of around 30-50 nm; attributed to its small molecular size.

Re:Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices .

Properties

Related CategoriesHole Transport (HT) & Hole Injection Layer (HIL) Materials, Hole Transport Materials, Materials Science, OLED and PLED Materials, Organic and Printed Electronics More...
InChI Key  XDXWNHPWWKGTKO-UHFFFAOYSA-N
assay  99% (HPLC)
mp  243-248 °C
absorption  306 nm in dichloromethane

385 nm in dichloromethane
fluorescence  λem 429 nm in dichloromethane

Description

Packaging

1, 5 g in glass bottle

Application

High-mobility material used for white OLEDs to increase hole injection and transport. It is the best solid-state hole transporting material, to date, used to replace the liquid electrolyte for DSSC solar cells, due to an excellent pore-filling property in nanoporous TiO2 film with pore size of around 30-50 nm; attributed to its small molecular size.


    Documents

    Certificate of Analysis


    Articles

    Recent Advances in Hybrid Halide Perovskites-based Solar Cells

    Kuppuswamy Kalyanasundaram, Shaik. M. Zakeeruddin, Michaël Grätzel* Laboratory for Photonics and Interfaces (LPI) Swiss Federal Institute of Technology at Lausanne (EPFL) 1015 Lausanne, Switzerland *...
    Kuppuswamy Kalyanasundaram, Shaik. M. Zakeeruddin, Michaël Grätzel
    Material Matters, 2016, 11.1, 3
    Keywords: Absorption, Atomic layer deposition, Capillary electrophoresis, Degradations, Deposition, Diffusion, Environmental, Infrared spectroscopy, Nanomaterials, Nanotubes, Nucleic acid annealing, Recombination, Semiconductor, Separation, Sol-gel, Solar cells, Solvents, Spectroscopy, Spin coating, Substitutions

    The Use of Perovskite Metal Complexes in Photovoltaic Cells

    Solar panels for homes and businesses have seen a rise in demand over the past few years as we move toward more environment-friendly and sustainable energy sources. In 2010, the average power from so...
    Dr. Avery Luedtke
    Senior Scientist, Sigma-Aldrich Materials Science.
    Keywords: Deposition, Semiconductor, Solar cells

    Understanding and Successfully Applying Materials for Dye-Sensitized Solar Cells

    Hans Desilvestro, Yanek Hebting, Mikael Khan, Damion Milliken Dyesol, Queanbeyan NSW 2620, Australia Email: yhebting#dyesol.com
    Keywords: Absorption, Adhesion, Adsorption, Bacterial conjugations, Calorimetry, Deposition, Diffusion, Electronics, Extinction coefficient, Hydroxylations, Ligands, Mass spectrometry, Nucleic acid annealing, Oxidations, PAGE, Printed electronics, Recombination, Reductions, Semiconductor, Solar cells, Solvents

Usage

   Usage of Spiro-OMeTAD from Inorganic caesium lead iodide perovskite solar cells,Giles E. Eperona, Giuseppe M. Paternòbc, Rebecca J. Suttona, Andrea Zampettibc, Amir Abbas Haghighirada,  Franco Caciallibc and Henry J. Snaitha* :

Subsequently substrates were transferred to nitrogen atmosphere and from this point, during fabrication

and testing, devices were never exposed to ambient air. Perovskite precursor was deposited as described

above. The hole-transporting layer was then deposited via spin-coating a solution of 86.9mg/ml of 2,2',7,7'-

tetrakis-(N,N-di-p-methoxyphenylamine)9,9'-spirobifluorene (spiro-OMeTAD) in chlorobenzene, with

additives of 9.7mg/ml Spiro(TFSI)2 prepared in-house following a published procedure,1 and 10μl/ml 4-tertbutylpyridine.

Spin-coating was carried out in a nitrogen-filled glovebox at 2000rpm. Gold electrodes were

then thermally evaporated under a vacuum of ~10-6 Torr, at a rate of ~0.1nm/s, to complete the devices.


Key details from references:

  • [1]: High efficiency      perovskite solar cells with >19% efficiency. Doping regime specified      via reference [2].

  • [2]: Spin coated      spiro-MeOTAD in chlorobenzene doped with the below compounds (doping      ratio's specified in reference [3]:

  • 4-tert-butylpyridine

  • lithium       bis(trifluoromethylsul-phonyl)imide (LiTFSI)

  • tris(2-(1H-pyrazol-1-yl)-4-tert-butylpyridine)cobalt(       III ) bis(tri-fluoromethylsulphonyl)imide

  • [3]: Doped with the below      concentrations

  • 50 mM spiro-OMeTAD in       chlorobenzene

  • Co( III )-complex       (FK209) first dissolved into an acetonitrile stock solution prepared with       concentrations in the range 4 to 33 mM before being added to the       Spiro/chlorobenzene solution

  • FK209 stock solution       mixed with Spiro/chlorobenzene solution to give overall 7.7 mol% FK209 to       Spiro-OMeTAD

  • Also doped with a stock       solution of Li-bis(trifluoromethanesulfonyl)imide (Li-TFSI) at 170 mg and       TBP at 46.6% by volume in acetonitrile

  • Spin-coated at 3000 rpm       for 30s


Category: Sublimed grade Spiro-OMeTAD

Related Category: Recrystallized grade Spiro-OMeTAD  Spiro-OMeTAD HTL  Spiro-OMeTAD derivatives 

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